Presentation
30 May 2022 Exploring the intrinsic limits of near-infrared detectors by novel materials design
Author Affiliations +
Abstract
Organic photodetectors (OPDs) with a performance comparable to that of conventional inorganic ones have recently been demonstrated for the visible regime.[1] However, near-infrared photodetection at a high detectivity has been proven to be more challenging and, to date, the true potential of organic semiconductors in this spectral range (800‒2500 nm) remains largely unexplored. We have recently shown that the main factor limiting the specific detectivity ( ) is non-radiative recombination, which is also known to be the main contributor to open-circuit voltage losses in organic photovoltaics.[2] Based on this finding we concluded that OPDs have the potential to be a useful technology up to 2 μm, given that high external quantum efficiencies can be maintained at these low photon energies. To further elaborate on the fundamentals defining these limitations, a next-generation of ‘defect-free’ organic semiconductors is synthesized. This allows us to investigate the influence of material imperfections (end-capping, homocoupling defects, and other impurities) on the material properties and device performance. In this contribution, we give an overview of the synthetic approaches applied and the latest organic semiconductors for high performance NIR OPDs, approaching their intrinsic limits. [1] N. Li et al., Mater. Sci. Adn Eng., 146, 100643 (2021) [2] S. Gielen et al., Adv. Mater., 32, 2003818 (2020)
Conference Presentation
© (2022) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Sam Gielen, Christina Kaiser, Jochen Vanderspikken, Omar Beckers, Ardalan Armin, Paul Meredith, Koen Vandewal, and Wouter Maes "Exploring the intrinsic limits of near-infrared detectors by novel materials design", Proc. SPIE PC12149, Organic Electronics and Photonics: Fundamentals and Devices III, PC121490G (30 May 2022); https://doi.org/10.1117/12.2620665
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KEYWORDS
Sensors

Organic semiconductors

Photodetectors

External quantum efficiency

Lithium

Near infrared

Organic photovoltaics

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