Gallium selenide nonlinear optical crystals are effective up- and down-converters of terahertz and infrared frequencies. Their nonlinear characteristics at the telecommunication wavelength have not received enough attention, particularly for sulfur-doped crystals. In order to close this gap, we put forward data on the optical and electro-optical characteristics of GaSe(1-x)Sx crystals (where x = 0, 0.03, 0.12, 0.16, and 0.22) at the wavelength of 1.55 micrometers and in the terahertz range. This study provides an estimate of the GaSe:S crystal’s nonlinear coefficient d22(ω1, ω2, ω3) responsible for the terahertz wave generation by means of optical rectification and difference frequency generation, where ω1 ≈ ω2 – corresponds to the near infrared range, and ω3 belongs to the subterahertz frequencies. We assume that the value of d22 lies within the range from 13.9 to 20.5 pm/V for the wavelengths of 0.63 to 1.55μm. The potential of S-doped GaSe crystals to be used as nonlinear optical converters for photonic devices operating at telecom wavelengths is discussed.
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