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At room temperature Tin hypothiodiphosphate (Sn2P2S6) belongs to spatial group Pc. The angle between its two optical axes is above 100°. The material is transparent from 0.53 to 8 μm with the bandgap close to 2.3 eV; it exhibits a pronounced photoconductivity. The crystallographic axis OX is nearly parallel to the axis of spontaneous polarization and the OY axis is normal to the mirror plane. Photorefractive recording inSn2P2S6 has been first accomplished in [1,2] with HeNe laser light. We report in this study on sensitizing of Sn2P2S6 crystals to cw-radiation of Nd3+:YAG laser (λ, = 1.06 μm) by pre-exposure to incoherent white light.
S. Odoulov
"New photorefractive ferroelectric for red and near infrared: tin hypothiodiphosphate", Proc. SPIE 2778, 17th Congress of the International Commission for Optics: Optics for Science and New Technology, 2778A5 (1 September 1996); https://doi.org/10.1117/12.2316054
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S. Odoulov, "New photorefractive ferroelectric for red and near infrared: tin hypothiodiphosphate," Proc. SPIE 2778, 17th Congress of the International Commission for Optics: Optics for Science and New Technology, 2778A5 (1 September 1996); https://doi.org/10.1117/12.2316054