Dissociation of metastable CH3CO radicals studied by time-resolved photofragment imaging

Toshinori Suzuki; Takeshi Shibata; Haiyang Li

doi:10.1117/12.308393

15 May 1998 Dissociation of metastable CH₃CO radicals studied by time-resolved photofragment imaging

Toshinori Suzuki, Takeshi Shibata, Haiyang Li

Proceedings Volume 3271, Laser Techniques for State-Selected and State-to-State Chemistry IV; (1998) https://doi.org/10.1117/12.308393
Event: Optoelectronics and High-Power Lasers and Applications, 1998, San Jose, CA, United States

Abstract

A novel experimental technique to measure the energy- dependent unimolecular dissociation rate k(E) of radical species is presented. Internally excited CH₃CO radicals were formed by ultraviolet photodissociation of CH₃COCl, and the subsequent decay of these radicals was detected by subpicosecond time-clocked photofragment imaging. The CH₃CO radicals with different internal energies were dispersed in space by their recoil velocities, and their decay rates were measured for each internal energy.

Citation Download Citation

Toshinori Suzuki, Takeshi Shibata, and Haiyang Li "Dissociation of metastable CH₃CO radicals studied by time-resolved photofragment imaging", Proc. SPIE 3271, Laser Techniques for State-Selected and State-to-State Chemistry IV, (15 May 1998); https://doi.org/10.1117/12.308393

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available