Spectroscopy of terrylene and perylene isolated in Kr matrix: investigation of multiplet structure

Iskander Biktchantaev; Vitaly V. Samartsev; Jerzy Sepiol

doi:10.1117/12.447972

15 November 2001 Spectroscopy of terrylene and perylene isolated in Kr matrix: investigation of multiplet structure

Iskander Biktchantaev, Vitaly V. Samartsev, Jerzy Sepiol

Proceedings Volume 4605, PECS 2001: Photon Echo and Coherent Spectroscopy; (2001) https://doi.org/10.1117/12.447972
Event: PECS'2001: Photon Echo and Coherent Spectroscopy, 2001, Novgorod, Russian Federation

Abstract

The low temperature (20 K) electronic absorption and emission spectra of terrylene (C₃₀H₁₆) and perylene (C₂₀H₁₂) isolated in Kr matrix are presented. The spectra of both chromophores reveal similar multiplet structure, and in each spectrum, six different sites were identified. In order to understand the origin of observed site-splitting, the theoretical calculations of complex system -- chromophore embedded into Kr matrix -- were carried out by means of MM+ method. The optimization of system structure yielded six different types (sites) of embedding chromophore molecules into Kr crystal lattice. As calculations have shown, the nearest environment of each embedding type distinguishes by its specific density of Kr atoms packing, on which basis the relationship between theoretically calculated sites and observed spectral features was established.

Citation Download Citation

Iskander Biktchantaev, Vitaly V. Samartsev, and Jerzy Sepiol "Spectroscopy of terrylene and perylene isolated in Kr matrix: investigation of multiplet structure", Proc. SPIE 4605, PECS 2001: Photon Echo and Coherent Spectroscopy, (15 November 2001); https://doi.org/10.1117/12.447972

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available