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The development of switchable mirrors based on yttrium hydride thin films is shown. Yttrium is deposited on regular glass under ultra-high vacuum conditions. Upon hydrogen pressure the transition from light-reflecting metal YH2 to transparent insulating YH3 is induced. Surface and optical characterization is performed to improve the deposition and hydrogenation conditions. A good variable transparency is achieved, with transmittance up to 70% in the visible range for the completely hydrogenated sample. The electronic structure of the YH3 phase is calculated by considering strong correlation corrections to the crystal potential. We obtain a gap in the quasiparticle spectrum that agrees with the optical transmittance of the YH3 phase. A prototype device based on these films is proposed.
M. M. Sanchez-Lopez,P. Velasquez,R. Castaner,A. Gutierrez,J. Costa-Quintana, andF. Lopez-Aguilar
"Yttrium hydride films as switchable mirrors: optical characterization and electronic structure", Proc. SPIE 4829, 19th Congress of the International Commission for Optics: Optics for the Quality of Life, (19 November 2003); https://doi.org/10.1117/12.531209
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M. M. Sanchez-Lopez, P. Velasquez, R. Castaner, A. Gutierrez, J. Costa-Quintana, F. Lopez-Aguilar, "Yttrium hydride films as switchable mirrors: optical characterization and electronic structure," Proc. SPIE 4829, 19th Congress of the International Commission for Optics: Optics for the Quality of Life, (19 November 2003); https://doi.org/10.1117/12.531209