A tunnel junction has been developed with an application to multijunction solar cells grown on GaSb and analyzed using a combination of electrical device measurements and modeling. The device employs an InAs quantum well embedded in a GaSb p/n junction, exploiting the high tunnel probability at the broken-gap interface between p-type GaSb and n-type InAs and having a minimal impact on the transparency of the device. The concept is extended to wider bandgap heterointerfaces using Al0.2Ga0.8Sb, achieving a differential resistance of 4.08×10−4  Ω cm2.

The impact of nonuniform spatial distribution of the luminescence coupling (LC) effect to the limiting cell conversion efficiency of multijunction solar cells (MJSCs) has been investigated. For this purpose, the laser beam induced current distribution maps of the limiting bottom cell have been acquired experimentally under varying middle-to-bottom cell LC efficiencies. The minimum and the maximum LC efficiencies demonstrated were 8.5% and 69%, respectively. To further analyze the measurement results, a quasi-two-dimensional simulation model considering the spatially nonuniform nature of the LC effect has been developed. A good agreement between the simulation and the measurement results suggests that the nonuniform LC current distribution is induced by optical phenomena such as photon escape and internal reflection. This nonuniformity then causes the absolute conversion efficiency of the limiting cell to be reduced by 1.35% at maximum LC efficiency. This reduction, when suppressed, can yield higher limiting cell conversion efficiency, which in turn may improve the overall MJSC conversion efficiency.

We report the fabrication of high performance inverted polymer solar cells with simply modified indium tin oxide (ITO) by an ultrathin aluminum (Al) and sodium chloride (NaCl) composite layer. The device efficiency and stability were both improved. The optimized device with poly(3-hexylthiophene) as the donor and [6,6]-phenyl-C61-butyric acid methylester as the acceptor under AM 1.5 (100  mw cm⁻²) radiation achieved a high power conversion efficiency of 3.88% with an open-circuit voltage of 0.60 V and a fill factor of 0.61, which is significantly higher than those of the inverted devices with only Al or NaCl as modification interlayer, respectively. Moreover, the stability is enhanced by about 70% more than that of the conventional device. The significant enhancement is attributed to the reduced work function of ITO electrode from 4.75 to 3.90 eV by modification as well as the improvement of the electrode interface.

A symmetrically stacked structure [(a-Si∶H(n⁺)/a-Si:H(i)/CZ wafer (n)/a-Si:H(i)/a-Si:H(n⁺)] was used to optimize the growth process conditions of the n-type hydrogenated amorphous silicon [a-Si∶H(n⁺)] thin films. Here a-Si:H(n⁺) film was used as back surface field (BSF) layer for the silicon heterojunction solar cell and all stacked films were prepared by conventional radio-frequency plasma-enhanced chemical vapor deposition. The characterizations of the effective carrier lifetime (τ_eff), electrical and structural properties, as well as correlation with the hydrogen dilution ratio (R = H₂∕SiH₄) were systematically discussed with the emphasis on the effectiveness of the passivation layer using the lifetime tester, spectroscopic ellipsometry, and hall measurement. High quality of a stacked BSF layer (intrinsic/n-type a-Si:H layer) with effective carrier lifetime of 1.8 ms can be consistently obtained. This improved passivation layer can be primarily attributed to the synergy of chemical and field effect to significantly reduce the surface recombination.

Harvesting solar energy is a promising solution toward meeting the world’s ever-growing energy demand. Dye-sensitized solar cells (DSSCs) are hybrid organic–inorganic solar cells with tremendous potential for commercial application, but they are plagued by inefficiency due to their poor sunlight absorption. Plasmonic silver nanoparticles (AgNPs) have been shown to enhance the absorptive properties of DSSCs, but their plasmonic resonance can cause thermal damage resulting in cell deterioration. Hence, the influence of Zr-doped TiO₂ on the efficiency of plasmon-enhanced DSSCs was studied, showing that 5 mol.% Zr-doping of the photoactive TiO₂ material can improve the photovoltaic performance of DSSCs by 44%. By examining three different DSSC designs, it became clear that the efficiency enhancing effect of Zr strongly depends on the proximity of the Zr-doped material to the plasmonic AgNPs.

Hematite is an appealing material for photoelectrochemical water splitting due to nearly ideal bandgap and Earth abundance. However, its short-distance hole transport has so far hindered exploiting its full potential. Two nanostructured transparent electrodes coated with a thin hematite layer are studied using full-field electromagnetic modeling. One structure comprises an ordered array of stripes of a transparent conductive oxide (TCO) and the other is composed of a square-lattice array of TCO nanorods. We find that height and filling ratio (FR) of the nanostructured elements constitutes the most crucial design parameter where the tall nanostructures with small FR constitute the ideal design for a nanostructured electrode with resonant-size elements. The simulations show that current densities up to 10.4  mA cm−2 can be obtained in a 20-nm thick hematite layer uniformly coated onto a properly designed nanostructured transparent conductive scaffold. Practical permittivity data are used in the simulation and the results show that these structures are quite robust against irregularities that might occur during the fabrications process.

The agglomeration/dewetting process of thin silver films provides a scalable method of obtaining self-assembled nanoparticles (SANPs) for plasmonics-based thin-film solar photovoltaic (PV) devices. We show the effect of annealing ambiance on silver SANP average size, particle/cluster finite shape, substrate area coverage/particle distribution, and how these physical parameters influence optical properties and surface-enhanced Raman scattering (SERS) responses of SANPs. Statistical analysis performed indicates that generally Ag SANPs processed in the presence of a gas (argon and nitrogen) ambiance tend to have smaller average size particles compared to those processed under vacuum. Optical properties are observed to be highly dependent on particle size, separation distance, and finite shape. The greatest SERS enhancement was observed for the argon-processed samples. There is a correlation between simulation and experimental data that indicate argon-processed AgNPs have a great potential to enhance light coupling when integrated to thin-film PV.

The International Energy Agency reports a 17.6% annual growth rate in sustainable energy production. However, sustainable power generation based on environmental conditions (wind and solar) requires an infrastructure that can handle intermittent power generation. An electromagnetic thermoelectric (EMTE) device to overcome the intermittency problems of current sustainable energy technologies, providing the continuous supply unachievable by photovoltaic cells with portability impossible for traditional thermoelectric (TE) generators, is proposed. The EMTE converts environmental electromagnetic waves to a voltage output without requiring additional input. A single cell of this TE-inspired broadband EMTE can generate a 19.50 nV output within a 7.2-μm² area, with a verified linear scalability of the output voltage through cell addition. This idea leads to a challenge: the electrical polarity of each row of cells is the same but may require additional routing to combine output from each row. An innovative layout is proposed to overcome this issue through switching the electrical polarity every other row. In this scheme, the EM wave absorption spectrum is not altered, and a simple series connection can be implemented to boost the total voltage output by 1 order within a limited area.