Paper
27 February 2019 Monitoring carrier transport and recombination in photovoltaic devices in real time
Y. Hazama, Y. Ishida, L. Zhu, C. Kim, S. Shin, H. Akiyama
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Abstract
Transport and recombination of excess carriers in an InGaAs solar cell are investigated by using time-resolved photoemission spectroscopy. We found that photovoltage rises and decays over 820 ps and 980 ps, respectively, at the pump fluence of 0.16 μJ/cm2. This result shows that charge separation and recombination occur in a close time scale while charge separation is substantially faster than recombination in a GaAs solar cell which we studied in the previous study. This implies that the InGaAs cell suffers from higher non-radiative recombination loss. We also analyze the limiting factor of the temporal resolution for the present technique. The temporal resolution can be improved by employing a light source with a higher photon energy while its benefit is not drastic. Alternative methods for the improvement are discussed. In addition, time-resolved photoluminescence spectroscopy was performed in order to compare the two time-resolved techniques. The photoluminescence decay of a GaAs cell shows a fast decay at a weak photo-injection level, which becomes slower at higher injection levels as observed in previous studies.
© (2019) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Y. Hazama, Y. Ishida, L. Zhu, C. Kim, S. Shin, and H. Akiyama "Monitoring carrier transport and recombination in photovoltaic devices in real time", Proc. SPIE 10913, Physics, Simulation, and Photonic Engineering of Photovoltaic Devices VIII, 109130Y (27 February 2019); https://doi.org/10.1117/12.2507736
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KEYWORDS
Solar cells

Photoemission spectroscopy

Photovoltaics

Solar energy

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