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Modern industrial lithium-ion batteries are susceptible to possible security concerns and early cell death due to typical organic fluid electrolytes' exceptionally high fluidity and combustibility properties. The holy grail for contemporary batteries with outstanding safety and high energy content is thought to be substituting fluid electrolytes with artificial solid-state equivalents and using Li metal anode electrodes. Yet, even though several prospective electrolytes made from solid-state materials have exceptionally high ionic conductivities, problems with the electrode/electrolyte interface end up being the main obstacle. The relationship between the chemistry of inorganic solid-state electrolytic solutions and the components of electrodes is given here, along with its difficulties and possibilities following current foundational knowledge. We will first concentrate on the features and processes of the interfacial arrangement, emphasizing that the dissatisfied interfacial reliability, equilibrium, and dendrites at issue are the primary barriers to developing high efficiency in the cells. The interface features such as contact/wettability, unchanged interfacial responses, insufficient interfacial Li+ stripping/plating manipulation, and Li dendrites that form the formation/propagation system will be examined accordingly.
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