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By means of combined calorimetric and luminescence method chemical singlet oxygen gas generators in which alkaline peroxide solutio is replaced by solid peroxihydrate compounds were investigated; the operating principle of the generators is based on the interaction of powder peroxihydrates and gaseous chlorine or liquid chlorine containing reagents. The optimal composition of synthesized solid compounds allows hydrogen peroxide to be transformed into singlet oxygen with efficiency up to 100%. The usage of working solids in comparison with liquid ones has a number of advantages related to simplicity and safety in operation of such gas generators, significant consumption characteristic improvement and overall dimensions reduction, four times the increase in singlet oxygen yield per unit weight of working components, and water steam content minimizing in the gas stream at the gas generator exit.
Yuri A. Kulagin,Victoria N. Yarygina, andGerman A. Skorobogatov
"Investigation of various types of singlet-oxygen generators", Proc. SPIE 1980, Iodine Lasers and Applications, (23 April 1993); https://doi.org/10.1117/12.144517
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Yuri A. Kulagin, Victoria N. Yarygina, German A. Skorobogatov, "Investigation of various types of singlet-oxygen generators," Proc. SPIE 1980, Iodine Lasers and Applications, (23 April 1993); https://doi.org/10.1117/12.144517