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The deposition of boron nitride and carbon nitride films by laser-induced plasma CVD was performed for the first time. The composition and structure of films grown in different experimental conditions was studied by methods of Raman spectroscopy and x-ray photoelectron spectroscopy. It was found that high fractions of sp3 C-N bonding in CN films and hexagonal type B-N bonding in BN films can be produced by this method. All the synthesized films were amorphous. The prospective for the development of B-C-N based compounds deposition by laser plasma technique is discussed.
Vladimir G. Ageev,M. V. Ugarov,E. N. Loubnin, andVitali I. Konov
"Pulsed-laser-driven plasma CVD of CN/BN compound films", Proc. SPIE 3484, Lasers in Synthesis, Characterization, and Processing of Diamond, (20 October 1998); https://doi.org/10.1117/12.328215
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Vladimir G. Ageev, M. V. Ugarov, E. N. Loubnin, Vitali I. Konov, "Pulsed-laser-driven plasma CVD of CN/BN compound films," Proc. SPIE 3484, Lasers in Synthesis, Characterization, and Processing of Diamond, (20 October 1998); https://doi.org/10.1117/12.328215