Corporate proton dynamics in delta-KIO3+HIO3 crystal as deduced from nu(OH) and delta(OH) band profiles

B. Engelen; T. Gavrilko; M. Panthofer; Galina A. Puchkovska; J. Baran; H. Ratajczak

doi:10.1117/12.486680

11 December 2002 Corporate proton dynamics in δ-KIO₃+HIO₃ crystal as deduced from ν(OH) and δ(OH) band profiles

B. Engelen, T. Gavrilko, M. Panthofer, Galina A. Puchkovska, J. Baran, H. Ratajczak

Proceedings Volume 4938, Selected Papers from the International Conference on Spectroscopy of Molecules and Crystals; (2002) https://doi.org/10.1117/12.486680
Event: XV International School on Spectroscopy of Molecules and Crystals, 2001, Chernivsti, Ukraine

Abstract

IR spectra of polycrystalline δ-KIO₃ HIO₃ have been studied in the temperature range from 13 to 300 K. A systematic temperature dependent study has been performed for the hydrogen bond stretching and bending vibrations. Features observed in the high frequency region of vibrational spectra of the title crystal are discussed with respect to possible formation of new charge compensating protonic species in the proton sublattice.

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B. Engelen, T. Gavrilko, M. Panthofer, Galina A. Puchkovska, J. Baran, and H. Ratajczak "Corporate proton dynamics in δ-KIO₃+HIO₃ crystal as deduced from ν(OH) and δ(OH) band profiles", Proc. SPIE 4938, Selected Papers from the International Conference on Spectroscopy of Molecules and Crystals, (11 December 2002); https://doi.org/10.1117/12.486680

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