Paper
1 March 2006 Fabrication of periodic arrays of top-gathering titania-organic hybrid pillars derived from multi-beam laser interference
Hiroyo Segawa, Hiroaki Misawa, Tetsuji Yano, Shuichi Shibata
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Abstract
Multi-beam laser interference (MLI) lithography is known to be one of the fabrication techniques of photonic crystals. In MLI lithography, laser beams are interfered on a scale of the wavelength of light and are irradiated to photosensitive films. We have paid attention to photosensitive TiO2-organic hybrid film, which has high refractive index. TiO2-organic hybrid periodic pillar patterns were fabricated by MLI lithography. The TiO2 hybrid film, which was prepared from Ti-alkoxide and β-diketone by the sol-gel method, was exposed to the interference pattern of femtosecond pulses at 800 nm wavelength. After laser irradiation, the unirradated portion was removed by the development and rinse. Two-dimensional periodic standing alone pillars and 2×2 and 3×3 top-gathering pillars, which were gathered at the top by means of self-organization were formed by changing conditions such as laser irradiation time and film thickness. The pillar patterns depended upon the rinse liquid, the diameter, and the height of pillars. The top-gathering pillars are applicable for diffractive optics.
© (2006) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Hiroyo Segawa, Hiroaki Misawa, Tetsuji Yano, and Shuichi Shibata "Fabrication of periodic arrays of top-gathering titania-organic hybrid pillars derived from multi-beam laser interference", Proc. SPIE 6106, Photon Processing in Microelectronics and Photonics V, 61060N (1 March 2006); https://doi.org/10.1117/12.647213
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Cited by 4 scholarly publications.
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KEYWORDS
Diffraction

Liquids

Lithography

Capillaries

Scanning electron microscopy

Femtosecond phenomena

Laser irradiation

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