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Extended X-ray absorption fine-structure (EXAFS) of the iron atoms in Cu98Fe2, Cu67Au30Fe3, and Cu69Au3oFel are used to provide direct structural information about the Fe enrivonments in these alloys. Fe in Cu98Fe2 is face-centered cubic γ-Fe, whereas Fe in the Cu-Au-Fe alloys is body-centered cubic α-Fe. These results are in excellent agreement with the results deduced from the Mossbauer studies of the hyperfine field distributions in these systems.
J. I. Budnick,M. Choi,D. M. Pease,Z. Tan,Guy H. Hayes,E. Klein, andB. Illerhaus
"Local Structural And Magnetic Environments Of Iron In Dilute Alloys", Proc. SPIE 0690, X-Rays in Materials Analysis: Novel Applications and Recent Developments, (12 August 1986); https://doi.org/10.1117/12.936599
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J. I. Budnick, M. Choi, D. M. Pease, Z. Tan, Guy H. Hayes, E. Klein, B. Illerhaus, "Local Structural And Magnetic Environments Of Iron In Dilute Alloys," Proc. SPIE 0690, X-Rays in Materials Analysis: Novel Applications and Recent Developments, (12 August 1986); https://doi.org/10.1117/12.936599