Multilayer optical coatings operating across broad spectral ranges from visible to mid-infrared play a crucial role in numerous industrial and scientific applications. MgF2, YF3, and Al2O3 are promising low-index materials within this range, Ge and Si can be harnessed as high-index materials. One of the key prerequisites to producing high-quality optical components is accurate knowledge of optical constants of thin-film materials as well as their environmental properties, which are dependent on deposition technology and process parameters. The present study reports characterization of monolayer samples of Ge, Si, YF3, Al2O3, and MgF2 on Silicon and Fused Silica substrates produced by e-beam evaporation with ion assistance technology. Deposition of the samples was performed at ORTUS-700 vacuum coater (IPhotonics). Reflectance and transmittance were measured using Photon RT spectrophotometer (Essent Optics) in the range 300-5000 nm. The samples were numerically characterized using advanced algorithms of OTF Studio software; layer optical constants were reliably determined.
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