Selective association of hydroxybenzenes with basket hosts: an FTIR study in dilute nonpolar solution

E. T.G. Lutz; John H. van der Maas; R. Sybesma; R. J. M. Nolte

doi:10.1117/12.56332

1 March 1992 Selective association of hydroxybenzenes with basket hosts: an FTIR study in dilute nonpolar solution

E. T.G. Lutz, John H. van der Maas, R. Sybesma, R. J. M. Nolte

Proceedings Volume 1575, 8th Intl Conf on Fourier Transform Spectroscopy; (1992) https://doi.org/10.1117/12.56332
Event: Eighth International Conference on Fourier Transform Spectroscopy, 1991, Lubeck-Travemunde, Germany

Abstract

Experimental evidence is found for different types of complexes that are formed when phenol and resorcinol associate with SmMe4 and Ph2RE basket type molecules. The symmetrical OH band of the complexes formed between resorcinol and SmMe4 is indicative for a bifurcated hydrogen bonded complex while the composed OH band in the other phenol, resorcinol complexes points to the presence of n and (pi) type OH(DOT)(DOT)(DOT)O equals C associates for SmMe4 and possibly additional OH(DOT)(DOT)(DOT)ether and OH(DOT)(DOT)(DOT)phenyl associates for Ph2RE.

Citation Download Citation

E. T.G. Lutz, John H. van der Maas, R. Sybesma, and R. J. M. Nolte "Selective association of hydroxybenzenes with basket hosts: an FTIR study in dilute nonpolar solution", Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); https://doi.org/10.1117/12.56332

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